List of Definitions assumed from Quantum Mechanics

The canonical commutation relation

\(\left[\hat{x},\hat{p}\right]=i\hbar\hat{\mathbb{I}}\)

Dirac notation

the notation \(|\psi\rangle\) for complex vectors. Also called bra-ket notation, with \(\langle\phi|\) the ‘bra’, \(|\psi\rangle\) the ‘ket’, and \(\langle\phi|\psi\rangle\) a bracket.

Expectation value

\(\langle\hat{A}\rangle=\langle\psi|\hat{A}|\psi\rangle\). The mean value of an operator measured by a given state.

First quantization

a wave-like description of quantum objects: \(\psi\left(x\right)\).

The Hamiltonian

the energy operator (assumed time independent in this course). \(\hat{H}=\hat{p}^{2}/2m+\hat{V}\), or \(\hat{H}\psi\left(x\right)=-\hbar^{2}\psi''/2m+V\left(x\right)\psi\).

The Heisenberg picture

the description of quantum states as time independent, and operators as time dependent.

The Heisenberg uncertainty principle

\(\sigma_{\hat{A}}\sigma_{\hat{B}}\ge\frac{1}{2}\left|\left\langle \left[\hat{A},\hat{B}\right]\right\rangle \right|\) where \(\sigma_{\hat{A}}\) denotes the standard deviation of operator \(\hat{A}\).

Hilbert space

a vector space with an inner product and square-normalisable vectors

Hermiticity

\(\hat{A}=\hat{A}^{\dagger}\) where \(\hat{A}^{\dagger}=\hat{A}^{*T}\). For differential operators: \(\int^{\infty}_{-\infty}\varphi\left(x\right)^{*}\left(\hat{A}\psi\left(x\right)\right)\text{d}x=\int^{\infty}_{-\infty}\left(\hat{A}\varphi\left(x\right)\right)^{*}\psi\left(x\right)\text{d}x\).

Ladder operators

an operator which raises or lowers the quantum number of a state it acts on. Also called creation/annihilation operators or raising and lowering operators.

Normalisation

the prefactor on a wavefunction ensuring that the total probability to find the particle is one.

The number operator

in the harmonic oscillator, the operator whose eigenstates are the energy eigenstates and whose eigenvalues are the level of the state.

Operators

objects which act on states to give states (either the same state, or a different one). In finite dimensional Hilbert spaces these are simply matrices acting on vectors to give vectors. In infinite dimensional Hilbert spaces they can be differential operators acting on functions to give functions.

Orthonormality

orthogonal and normalised. If a set of states is orthonormal the inner product of any state with itself is 1 and the inner product between any two different states is zero.

The probability density \(\rho\)

integrated over a region of space, this gives the probability to find the particle in that region. \(\rho\left(x,t\right)\text{d}x=\left|\psi\left(x,t\right)\right|^{2}\text{d}x\) is the probability to find the particle between \(x\) and \(x+\text{d}x\) at time \(t\).

The probability current density \(j\)

the current density associated with a flow of probability: \(\boldsymbol{j}\left(\boldsymbol{x},t\right)=\frac{i\hbar}{2m}\left\{ \psi\nabla\psi^{*}-\psi^{*}\nabla\psi\right\}\).

The probability amplitude

the complex number associated to each point in space by the wavefunction \(\psi\).

Quantum numbers

eigenvalues of operators which commute with the Hamiltonian; expectation values which do not change in time.

The Schrodinger picture

the description of quantum states as time dependent, and operators as time independent.

Second quantisation

a particle-like description of quantum objects in terms of ladder operators.

Stationary states

energy eigenstates. So called as their probability densities are time independent.

Superposition

summing solutions to the TDSE to get a new solution to the TDSE

The time dependent schroedinger equation

\(i\hbar\partial_{t}|\psi\rangle=\hat{H}|\psi\rangle\), or in the position basis \(i\hbar\dot{\psi}=\hat{H}\psi\). Abbreviated TDSE.

The time independent schroedinger equation

\(\hat{H}|\psi\rangle=E|\psi\rangle\), or in the position basis \(\hat{H}\psi\left(x\right)=E\psi\left(x\right)\). Abbreviated TISE.

The wavefunction \(\psi\)

a function which assigns a complex number to each point in space. The modulus square is the probability density \(\rho\).